Strong chemicals.....?
You know in movies when someone puts a cloth over someone's mouth and nose? What chemicals would be on their that would knock them out so fast? No I'm not going to do it, just curious.
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hkhrbp,
Back in the "old days", they used chloroform (or so they said) in the movies. Another "quick" anesthetic is diethyl ether (sometimes just called "ether").
Hope that helped!